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Thursday, March 19, 2009

Alloys of potassium

Alloys of potassium: - Potassium is a chemical element. It has the symbol K (Latin: kalium, from Arabic: القَلْيَهal-qalyah “plant ashes”, cf. Alkali from the same root), atomic number 19, and atomic mass 39.0983. Potassium was first isolated from potash, hence the name. Elemental potassium is a soft silvery-white metallic alkali metal that oxidizes rapidly in air and is very reactive with water, generating sufficient heat to ignite the evolved hydrogen.

Potassium in nature occurs only as ionic salt. As such, it is found dissolved in seawater, and as part of many minerals. Potassium ion is necessary for the function of all living cells, and is thus present in all plant and animal tissues. It is found in especially high concentrations in plant cells, and in a mixed diet, it is most highly concentrated in fruits.

In many respects, potassium and sodium are chemically similar, although they have very different functions in organisms in general, and in animal cells in particular.

Precautions: - Potassium reacts very violently with water producing hydrogen gas which then usually catches fire. Potassium is usually kept under a hydrocarbon oil such as mineral oil or kerosene to stop the metal from reacting with water vapour present in the air. Unlike lithium and sodium, however, potassium should not be stored under oil indefinitely. If stored longer than 6 months to a year, dangerous shock-sensitive peroxides can form on the metal and under the lid of the container, which can detonate upon opening. It is recommended that potassium, rubidium or caesium not be stored for longer than three months unless stored in an inert (oxygen free) atmosphere, or under vacuum.[29]

As potassium reacts with water to produce highly flammable hydrogen gas, a potassium fire is only exacerbated by the addition of water, and only a few dry chemicals are effective for putting out such a fire (see the precaution section in sodium).

Potassium also produces potassium hydroxide (KOH) in the reaction with water. Potassium hydroxide is a strong alkali and so is a caustic hazard, causing burns.

Due to the highly reactive nature of potassium metal, it must be handled with great care, with full skin and eye protection being used and preferably an explosive resistant barrier between the user and the potassium.

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